An unprecedentedly huge square-grid copper(II)-organic framework material built from a bulky pyrene-derived elongated cross-shaped scaffold.

نویسندگان

  • Chen-Chuan Tsai
  • Tzuoo-Tsair Luo
  • Jen-Fu Yin
  • Hong-Cheu Lin
  • Kuang-Lieh Lu
چکیده

A new bulky pyrene-derived elongated cross-shaped organic scaffold was successfully incorporated into a highly porous, noninterpenetrated square-grid copper(II)-organic framework material with the unprecedentedly huge dimensions of 25.5 x 25.5 A(2), while the layer-to-layer NH...N interaction leads to a unique hydrogen-bonded 6(4).8(2)-nbo net.

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عنوان ژورنال:
  • Inorganic chemistry

دوره 48 18  شماره 

صفحات  -

تاریخ انتشار 2009